Assessment of human health risk from potentially toxic elements and predicting groundwater contamination using machine learning approaches.

The Rooppur Nuclear Power Plant (RNPP) at Ishwardi, Bangladesh is planning to go into operation within 2024 and therefore, adjacent areas of RNPP is gaining adequate attention from the scientific community for environmental monitoring purposes especially for water resources management. However, there is a substantial lack of literature as well as environmental datasets for earlier years since very little was done at the beginning of the RNPP's construction phase. Therefore, this study was conducted to assess the potential toxic elements (PTEs) contamination in the groundwater and its associated health risk for residents at the adjacent part of the RNPP during the year of 2014-2015. For the purposes of achieving the aim of the study, groundwater samples were collected seasonally (dry and wet season) from nine sampling sites and afterwards analyzed for water quality indicators such as temperature (Temp.), pH, electrical conductivity (EC), total dissolved solid (TDS), total hardness (TH) and for PTEs including Iron (Fe), Manganese (Mn), Copper (Cu), Lead (Pb), Chromium (Cr), Cadmium (Cd) and Arsenic (As). This study adopted the newly developed Root Mean Square water quality index (RMS-WQI) model to assess the scenario of contamination from PTEs in groundwater whereas the human health risk assessment model was utilized to quantify the risk of toxicity from PTEs. In most of the sampling sites, PTEs concentration was found higher during the wet season than the dry season and Fe, Mn, Cd and As exceeded the guideline limit for drinking water. The RMS score mostly classified the groundwater in terms of PTEs contamination into "Fair" condition. The non-carcinogenic risks (expressed as Hazard Index-HI) revealed that around 44% and 89% of samples for adults and 67% and 100% of samples for children exceeded the threshold limit set by USEPA (HI > 1) and possessed risks through the oral pathway during dry and wet season, respectively. Furthermore, the calculated cumulative HI score was found higher for children than the adults throughout the study period. In terms of carcinogenic risk (CR) from PTEs, the magnitude of risk decreased following the pattern of Cr > As > Cd. Although the current study is based on old dataset, the findings might serve as a baseline for monitoring purposes to reduce future hazardous impact from the power plant.

Assessment of hydrogeochemistry in groundwater using water quality index model and indices approaches.

Groundwater resources around the world required periodic monitoring in order to ensure the safe and sustainable utilization for humans by keeping the good status of water quality. However, this could be a daunting task for developing countries due to the insufficient data in spatiotemporal resolution. Therefore, this research work aimed to assess groundwater quality in terms of drinking and irrigation purposes at the adjacent part of the Rooppur Nuclear Power Plant (RNPP) in Bangladesh. For the purposes of achieving the aim of this study, nine groundwater samples were collected seasonally (dry and wet season) and seventeen hydro-geochemical indicators were analyzed, including Temperature (Temp.), pH, electrical conductivity (EC), total dissolved solids (TDS), total alkalinity (TA), total hardness (TH), total organic carbon (TOC), bicarbonate (HCO3-), chloride (Cl-), phosphate (PO43-), sulfate (SO42-), nitrite (NO2-), nitrate (NO3-), sodium (Na+), potassium (K+), calcium (Ca2+) and magnesium (Mg2+). The present study utilized the Canadian Council of Ministers of the Environment water quality index (CCME-WQI) model to assess water quality for drinking purposes. In addition, nine indices including EC, TDS, TH, sodium adsorption ratio (SAR), percent sodium (Na%), permeability index (PI), Kelley's ratio (KR), magnesium hazard ratio (MHR), soluble sodium percentage (SSP), and Residual sodium carbonate (RSC) were used in this research for assessing the water quality for irrigation purposes. The computed mean CCME-WQI score found higher during the dry season (ranges 48 to 74) than the wet season (ranges 40 to 65). Moreover, CCME-WQI model ranked groundwater quality between the "poor" and "marginal" categories during the wet season implying unsuitable water for human consumption. Like CCME-WQI model, majority of the irrigation index also demonstrated suitable water for crop cultivation during dry season. The findings of this research indicate that it requires additional care to improve the monitoring programme for protecting groundwater quality in the RNPP area. Insightful information from this study might be useful as baseline for national strategic planners in order to protect groundwater resources during the any emergencies associated with RNPP.

Assessing the impact of COVID-19 lockdown on surface water quality in Ireland using advanced Irish water quality index (IEWQI) model.

The COVID-19 pandemic has significantly impacted various aspects of life, including environmental conditions. Surface water quality (WQ) is one area affected by lockdowns imposed to control the virus's spread. Numerous recent studies have revealed the considerable impact of COVID-19 lockdowns on surface WQ. In response, this research aimed to assess the impact of COVID-19 lockdowns on surface water quality in Ireland using an advanced WQ model. To achieve this goal, six years of water quality monitoring data from 2017 to 2022 were collected for nine water quality indicators in Cork Harbour, Ireland, before, during, and after the lockdowns. These indicators include pH, water temperature (TEMP), salinity (SAL), biological oxygen demand (BOD5), dissolved oxygen (DOX), transparency (TRAN), and three nutrient enrichment indicators-dissolved inorganic nitrogen (DIN), molybdate reactive phosphorus (MRP), and total oxidized nitrogen (TON). The results showed that the lockdown had a significant impact on various WQ indicators, particularly pH, TEMP, TON, and BOD5. Over the study period, most indicators were within the permissible limit except for MRP, with the exception of during COVID-19. During the pandemic, TON and DIN decreased, while water transparency significantly improved. In contrast, after COVID-19, WQ at 7% of monitoring sites significantly deteriorated. Overall, WQ in Cork Harbour was categorized as "good," "fair," and "marginal" classes over the study period. Compared to temporal variation, WQ improved at 17% of monitoring sites during the lockdown period in Cork Harbour. However, no significant trend in WQ was observed. Furthermore, the study analyzed the advanced model's performance in assessing the impact of COVID-19 on WQ. The results indicate that the advanced WQ model could be an effective tool for monitoring and evaluating lockdowns' impact on surface water quality. The model can provide valuable information for decision-making and planning to protect aquatic ecosystems.

Marine waters assessment using improved water quality model incorporating machine learning approaches.

In marine ecosystems, both living and non-living organisms depend on "good" water quality. It depends on a number of factors, and one of the most important is the quality of the water. The water quality index (WQI) model is widely used to assess water quality, but existing models have uncertainty issues. To address this, the authors introduced two new WQI models: the weight based weighted quadratic mean (WQM) and unweighted based root mean squared (RMS) models. These models were used to assess water quality in the Bay of Bengal, using seven water quality indicators including salinity (SAL), temperature (TEMP), pH, transparency (TRAN), dissolved oxygen (DOX), total oxidized nitrogen (TON), and molybdate reactive phosphorus (MRP). Both models ranked water quality between "good" and "fair" categories, with no significant difference between the weighted and unweighted models' results. The models showed considerable variation in the computed WQI scores, ranging from 68 to 88 with an average of 75 for WQM and 70 to 76 with an average of 72 for RMS. The models did not have any issues with sub-index or aggregation functions, and both had a high level of sensitivity (R2 = 1) in terms of the spatio-temporal resolution of waterbodies. The study demonstrated that both WQI approaches effectively assessed marine waters, reducing uncertainty and improving the accuracy of the WQI score.

Assessing the impact of land use and land cover on river water quality using water quality index and remote sensing techniques.

The impact of land use on water quality is becoming a global concern due to the increasing demand for freshwater. This study aimed to assess the effects of land use and land cover (LULC) on the surface water quality of the Buriganga, Dhaleshwari, Meghna, and Padma river system in Bangladesh. To determine the state of water, water samples were collected from twelve locations in the Buriganga, Dhaleshwari, Meghna, and Padma rivers during the winter season of 2015 and collected samples were analysed for seven water quality indicators: pH, temperature (Temp.), conductivity (Cond.), dissolved oxygen (DO), biological oxygen demand (BOD), nitrate nitrogen (NO3-N), and soluble reactive phosphorus (SRP) for assessing water quality (WQ). Additionally, same-period satellite imagery (Landsat-8) was utilised to classify the LULC using the object-based image analysis (OBIA) technique. The overall accuracy assessment and kappa co-efficient value of post-classified images were 92% and 0.89, respectively. In this research, the root mean squared water quality index (RMS-WQI) model was used to determine the WQ status, and satellite imagery was utilised to classify LULC types. Most of the WQs were found within the ECR guideline level for surface water. The RMS-WQI result showed that the "fair" status of water quality found in all sampling sites ranges from 66.50 to 79.08, and the water quality is satisfactory. Four types of LULC were categorised in the study area mainly comprised of agricultural land (37.33%), followed by built-up area (24.76%), vegetation (9.5%), and water bodies (28.41%). Finally, the Principal component analysis (PCA) techniques were used to find out significant WQ indicators and the correlation matrix revealed that WQ had a substantial positive correlation with agricultural land (r = 0.68, P < 0.01) and a significant negative association with the built-up area (r = - 0.94, P < 0.01). To the best of the authors' knowledge, this is the first attempt in Bangladesh to assess the impact of LULC on the water quality along the longitudinal gradient of a vast river system. Hence, we believe that the findings of this study can support planners and environmentalists to plan and design landscapes and protect the river environment.